this post was submitted on 10 Oct 2024
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collapse of the old society

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[–] TheRealCharlesEames@lemm.ee 3 points 4 weeks ago (3 children)

Is reverse osmosis enough or do I need a fancy PFAS filter too?

[–] Yeromon@discuss.tchncs.de 3 points 4 weeks ago (1 children)
[–] averyminya 1 points 3 weeks ago

But I'm assuming it's with that weird effect where it gets 90% the first time but then that remaining 10% needs to be done like 40 times before it's "100%"

[–] ProdigalFrog@slrpnk.net 2 points 3 weeks ago* (last edited 3 weeks ago) (1 children)

If you already have reverse osmosis, you're probably good.

As a long cost option for others reading this, apparently the activated charcoal Berkey filters remove 100% of PFAS, and due to the filters being rated to last 8 years of continuous use, are exceptionally affordable.

To bring the costs even lower, you can just buy the filters and not the expensive stainless steel containers by drilling some holes in a 5gal plastic bucket for the filters (it's gravity fed) and place another bucket below to collect it.

[–] I_am_10_squirrels 4 points 3 weeks ago (1 children)

Thanks for the recommendation. They had to change the name after a Stop Sale order from the EPA for claims about filtering microbes. They're now Boroux filters.

One caution I have about carbon filters is regarding breakthrough. Activated carbon works through the contaminants "sticking" to it. Some contaminats are stickier than others. If a really sticky something comes along, it will knock off the less sticky thing that was already there. Hopefully this less sticky thing will restick further down the column, but there's a possibility for it to breakthrough into the filtered water. Imagine you're at a party with a friend and someone they like better shows up. The new person is stickier so you get knocked off. Now you can find someone else to hang out with, or just leave the party.

The particles like PFAS and microplastics are likely getting trapped in the pore space rather than being stuck to the carbon. This means that they won't come unstuck, but they will decrease the flow rate through the filter. Like having a car break down and block a lane of traffic.

[–] phil_stevens@mastodon.nz 2 points 3 weeks ago (1 children)

@I_am_10_squirrels @ProdigalFrog There is more to it than just molecules getting "trapped in pore spaces" and it's a little complicated.

Activated carbon (and its more affordable, carbon-sequestering cousin #biochar) has functional attachment points on the edges of ring and plate molecular structures. These can attract and retain some substances from solution.

But the real fun happens when we add dopants. Other molecules present in the carbon matrix supercharge the chemical potential.

1/2

[–] phil_stevens@mastodon.nz 2 points 3 weeks ago (1 children)

@I_am_10_squirrels @ProdigalFrog The most exciting announcement I've seen in a long time is this one:

https://www.nature.com/articles/s44172-024-00267-4

Adding iron to biochar gives it the ability to adsorb *and* destroy PFAS in contaminated water. This is a product that can be produced relatively cheaply and contribute to drawdown of atmospheric CO2, and effectively degrades hazardous fluorocarbon pollutants with minimal disposal headaches after the fact.

2/2

[–] robloblaw@mastodon.social 2 points 3 weeks ago (2 children)

@phil_stevens @I_am_10_squirrels @ProdigalFrog
That is amazingly important. Sounds like something that could be done economically at all water treatment plants.

[–] phil_stevens@mastodon.nz 1 points 3 weeks ago

@robloblaw @I_am_10_squirrels @ProdigalFrog It's dead simple and apparently the breakdown happens without the UV exposure, albeit more slowly. The material itself does not degrade significantly and can be reused many times before replenishing.

[–] robloblaw@mastodon.social 1 points 3 weeks ago* (last edited 3 weeks ago) (1 children)

@phil_stevens @I_am_10_squirrels @ProdigalFrog
The only other way to destroy this class of chemicals is burning at over 1000C. Even then, you end up with a bunch of similarly problematic shorter chain fluorinated hydrocarbons.

[–] phil_stevens@mastodon.nz 2 points 3 weeks ago

@robloblaw @I_am_10_squirrels @ProdigalFrog Exactly why they are such a fiendish problem and also why catalytic processes are the way to go.

[–] mle86@feddit.org 1 points 3 weeks ago* (last edited 3 weeks ago)

No clue, but I wouldn't even be surprised if parts of filtration systems use PFAS themselves as coatings or similar, to reduce friction in pumps, for water proofing etc.