I'm most comfortable using Manjaro Cinnamon right now. It was familiar enough coming from Windows.
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Maybe it's just that it's familiar, but Zorin OS has always had the most "it just works" GUI to me. It's clean, stable, and provides many sensible presets if you prefer windows environments, mac environments, old school gnome, etc.
Aside from being very pretty it also has great UX and linux beginner onboarding features. For example if you try to open an exe file for the first time, it explains that this is a Windows-specific file and sets up Wine for you.
A lot of people recommend Fedora and PopOS for people getting into Linux but honestly Zorin Core has always been my #1.